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Combining visible light catalysis and transfer hydrogenation for in situ efficient and selective semihydrogenation of alkynes under ambient conditions.
Zhong, Jian-Ji; Liu, Qiang; Wu, Cheng-Juan; Meng, Qing-Yuan; Gao, Xue-Wang; Li, Zhi-Jun; Chen, Bin; Tung, Chen-Ho; Wu, Li-Zhu.
Affiliation
  • Zhong JJ; Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & University of the Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190, P. R. China. lzwu@mail.ipc.ac.cn.
  • Liu Q; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, P. R. China.
  • Wu CJ; Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & University of the Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190, P. R. China. lzwu@mail.ipc.ac.cn.
  • Meng QY; Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & University of the Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190, P. R. China. lzwu@mail.ipc.ac.cn.
  • Gao XW; Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & University of the Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190, P. R. China. lzwu@mail.ipc.ac.cn.
  • Li ZJ; Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & University of the Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190, P. R. China. lzwu@mail.ipc.ac.cn.
  • Chen B; Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & University of the Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190, P. R. China. lzwu@mail.ipc.ac.cn.
  • Tung CH; Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & University of the Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190, P. R. China. lzwu@mail.ipc.ac.cn.
  • Wu LZ; Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & University of the Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190, P. R. China. lzwu@mail.ipc.ac.cn.
Chem Commun (Camb) ; 52(9): 1800-3, 2016 Jan 31.
Article de En | MEDLINE | ID: mdl-26593867
ABSTRACT
By combining visible light catalysis and transfer hydrogenation, we are able to convert a series of alkynes to their corresponding alkenes in high chemical yields. Then the visible light catalytic transfer hydrogenation reaction can couple photoisomerization to produce E-alkenes or Z-alkenes exclusively depending on the aryl or alkyl substituted alkynes.
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Texte intégral: 1 Collection: 01-internacional Base de données: MEDLINE Langue: En Journal: Chem Commun (Camb) Sujet du journal: QUIMICA Année: 2016 Type de document: Article
Texte intégral
Ajouter à My VHL
Imprimer
XML
PubMed Links
Recherche sur Google

Texte intégral: 1 Collection: 01-internacional Base de données: MEDLINE Langue: En Journal: Chem Commun (Camb) Sujet du journal: QUIMICA Année: 2016 Type de document: Article