Platinum(ii) photo-catalysis for highly selective difluoroalkylation reactions.
Chem Commun (Camb)
; 53(64): 8948-8951, 2017 Aug 08.
Article
de En
| MEDLINE
| ID: mdl-28675221
ABSTRACT
The platinum(ii) photo-catalyzed difluoroalkylation of cinnamic acids and alkynes for selective construction of E-,Z-difluoroalkyl alkenes and difluoroalkyl alkenyl iodides, respectively, were achieved under mild conditions. The high efficiency, good substrate scope and high selectivity altogether highlight the prospect of Pt(ii) photocatalysts in visible-light-driven organic transformation reactions.
Texte intégral:
1
Collection:
01-internacional
Base de données:
MEDLINE
Langue:
En
Journal:
Chem Commun (Camb)
Sujet du journal:
QUIMICA
Année:
2017
Type de document:
Article