Pd-Catalyzed C(sp2)-H aminocarbonylation using the Langlois reagent as a carbonyl source.
Org Biomol Chem
; 16(35): 6438-6442, 2018 09 11.
Article
de En
| MEDLINE
| ID: mdl-30140800
ABSTRACT
A Pd-catalyzed C(sp2)-H aminocarbonylation of aryl carboxamides assisted by an N,S-bidentate directing group was developed, in which cheap and stable sodium trifluoromethanesulfinate was first utilized as a carbonyl source. The reaction can be applicable to a wide range of carboxamides with good functional group tolerance and afford isoindole-1,3-diones in moderate to good yields.
Texte intégral:
1
Collection:
01-internacional
Base de données:
MEDLINE
Langue:
En
Journal:
Org Biomol Chem
Sujet du journal:
BIOQUIMICA
/
QUIMICA
Année:
2018
Type de document:
Article