Self-assembly of a Si-based cage by the formation of 24 equivalent covalent bonds.

Holmes, Jessica L; Abrahams, Brendan F; Ahveninen, Anna; Boughton, Berin A; Hudson, Timothy A; Robson, Richard; Thinagaran, Dinaiz

Holmes, Jessica L; Abrahams, Brendan F; Ahveninen, Anna; Boughton, Berin A; Hudson, Timothy A; Robson, Richard; Thinagaran, Dinaiz.

Affiliation

Holmes JL; School of Chemistry, University of Melbourne, Victoria 3010, Australia. bfa@unimelb.edu.au r.robson@unimelb.edu.au.
Abrahams BF; School of Chemistry, University of Melbourne, Victoria 3010, Australia. bfa@unimelb.edu.au r.robson@unimelb.edu.au.
Ahveninen A; School of Chemistry, University of Melbourne, Victoria 3010, Australia. bfa@unimelb.edu.au r.robson@unimelb.edu.au.
Boughton BA; Metabolomics Australia, School of Biosciences, University of Melbourne, Parkville, Victoria 3010, Australia.
Hudson TA; School of Chemistry, University of Melbourne, Victoria 3010, Australia. bfa@unimelb.edu.au r.robson@unimelb.edu.au.
Robson R; School of Chemistry, University of Melbourne, Victoria 3010, Australia. bfa@unimelb.edu.au r.robson@unimelb.edu.au.
Thinagaran D; Metabolomics Australia, School of Biosciences, University of Melbourne, Parkville, Victoria 3010, Australia.

Chem Commun (Camb) ; 54(84): 11877-11880, 2018 Oct 28.

Article de En | MEDLINE | ID: mdl-30283934

ABSTRACT

ABSTRACT

A robust, nano-sized covalent cage, of composition, [(PhSi)6(ctc)4]6- (H6ctc = cyclotricatechylene) has been prepared in a simple reaction in good yield. The tetrahedral anionic cage is stable in both the solid and solution state and exhibits an affinity for Cs+ ions which bind to the internal surface of the cage.

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Texte intégral: 1 Collection: 01-internacional Base de données: MEDLINE Langue: En Journal: Chem Commun (Camb) Sujet du journal: QUIMICA Année: 2018 Type de document: Article

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