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[Am(C5 Me4 H)3 ]: An Organometallic Americium Complex.
Goodwin, Conrad A P; Su, Jing; Albrecht-Schmitt, Thomas E; Blake, Anastasia V; Batista, Enrique R; Daly, Scott R; Dehnen, Stefanie; Evans, William J; Gaunt, Andrew J; Kozimor, Stosh A; Lichtenberger, Niels; Scott, Brian L; Yang, Ping.
Affiliation
  • Goodwin CAP; Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM, 87545, USA.
  • Su J; Theoretical Division, Los Alamos National Laboratory, Los Alamos, NM, 87545, USA.
  • Albrecht-Schmitt TE; Department of Chemistry and Biochemistry, Florida State University, 95 Chieftain Way, Tallahassee, FL, 32306, USA.
  • Blake AV; Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM, 87545, USA.
  • Batista ER; Department of Chemistry, University of Iowa, E311 Chemistry Building, Iowa City, IA, 52245-1294, USA.
  • Daly SR; Theoretical Division, Los Alamos National Laboratory, Los Alamos, NM, 87545, USA.
  • Dehnen S; Department of Chemistry, University of Iowa, E311 Chemistry Building, Iowa City, IA, 52245-1294, USA.
  • Evans WJ; Fachbereich Chemie und Wissenschaftliches Zentrum für Materialwissenschaften, Philipps-Universität Marburg, Hans-Meerwein-Strasse 4, 35043, Marburg, Germany.
  • Gaunt AJ; Department of Chemistry, University of California, Irvine 1102 Natural Sciences II, Irvine, CA, 92697-2025, USA.
  • Kozimor SA; Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM, 87545, USA.
  • Lichtenberger N; Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM, 87545, USA.
  • Scott BL; Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM, 87545, USA.
  • Yang P; Fachbereich Chemie und Wissenschaftliches Zentrum für Materialwissenschaften, Philipps-Universität Marburg, Hans-Meerwein-Strasse 4, 35043, Marburg, Germany.
Angew Chem Int Ed Engl ; 58(34): 11695-11699, 2019 Aug 19.
Article de En | MEDLINE | ID: mdl-31190446
ABSTRACT
We report the small-scale synthesis, isolated yield, single-crystal X-ray structure, 1 H NMR solution spectroscopy /solid-state UV/Vis-nIR spectroscopy, and density functional theory (DFT)/ab initio wave function theory calculations on an Am3+ organometallic complex, [Am(C5 Me4 H)3 ] (1). This constitutes the first quantitative data on Am-C bonding in a molecular species.
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Texte intégral: 1 Collection: 01-internacional Base de données: MEDLINE Langue: En Journal: Angew Chem Int Ed Engl Année: 2019 Type de document: Article Pays d'affiliation: États-Unis d'Amérique
Texte intégral
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Texte intégral: 1 Collection: 01-internacional Base de données: MEDLINE Langue: En Journal: Angew Chem Int Ed Engl Année: 2019 Type de document: Article Pays d'affiliation: États-Unis d'Amérique