Visible-Light Flow Reactor Packed with Porous Carbon Nitride for Aerobic Substrate Oxidations.
ACS Appl Mater Interfaces
; 12(7): 8176-8182, 2020 Feb 19.
Article
de En
| MEDLINE
| ID: mdl-31962048
ABSTRACT
A triphasic photocatalytic reactor employing a mesoporous carbon nitride photocatalyst and aerobic O2 was assembled to operate under continuous flow conditions. This reactor design allows for facile downstream processing and reusability in multiple flow cycles. The selective aerobic oxidation of alcohols and amines was chosen to demonstrate the applicability and performance advantage of this flow approach compared to that of conventional batch photochemistry. This precious-metal-free photocatalytic flow system operates under benign reaction conditions (visible light, low pressure, and mild temperature) and will stimulate the exploration of other oxidative reactions in a sustainable, scalable, and affordable manner.
Texte intégral:
1
Collection:
01-internacional
Base de données:
MEDLINE
Langue:
En
Journal:
ACS Appl Mater Interfaces
Sujet du journal:
BIOTECNOLOGIA
/
ENGENHARIA BIOMEDICA
Année:
2020
Type de document:
Article
Pays d'affiliation:
Royaume-Uni