Preparation of natural rubber based semi-IPNs superabsorbent and its adsorption behavior for ammonium.

ABSTRACT

In this study, a natural rubber (NR) based amphiphilic semi-interpenetrating polymer network (semi-IPN) superabsorbent hydrogel was designed and synthesized with natural rubber-graft-poly (acrylic acid-co-acrylamide) [NR-g-P(AA-co-AM)] network and linear poly (diallyldimethyl ammonium chloride) (PDADMAC). Through a series of characterization and test, the structure, morphology, thermal properties, biodegradation, and swelling properties of NR-g-P(AA-co-AM)/PDADMAC were determined. Subsequently, NR-g-P(AA-co-AM)/PDADMAC was used for ammonium adsorption to remove ammonium nitrogen in aqueous solution. The adsorption behavior of the absorbent was also studied. Results showed that the maximum water absorbency of NR-g-P(AA-co-AM)/PDADMAC was 112.04 ± 6.55 g/g and water retention capacity of soil with the superabsorbent was 115.62 ± 2.08%. The NH4+ adsorption quickly reached equilibrium and the maximum adsorption capacity was 13.02 mmol g-1 calculated from Langmuir isotherm model. The results suggest that the product is efficient for ammonium removal and can be used as water-retaining agents.