Selective Oxidation of Ethane to Acetic Acid Catalyzed by a C-Scorpionate Iron(II) Complex: A Homogeneous vs. Heterogeneous Comparison.
Molecules
; 25(23)2020 Nov 30.
Article
de En
| MEDLINE
| ID: mdl-33266077
ABSTRACT
The direct, one-pot oxidation of ethane to acetic acid was, for the first time, performed using a C-scorpionate complex anchored onto a magnetic core-shell support, the Fe3O4/TiO2/[FeCl2{κ3-HC(pz)3}] composite. This catalytic system, where the magnetic catalyst is easily recovered and reused, is highly selective to the acetic acid synthesis. The performed green metrics calculations highlight the "greeness" of the new ethane oxidation procedure.
Mots clés
Texte intégral:
1
Collection:
01-internacional
Base de données:
MEDLINE
Sujet principal:
Composés du fer
/
Acide acétique
/
Éthane
/
Complexes de coordination
Type d'étude:
Prognostic_studies
Langue:
En
Journal:
Molecules
Sujet du journal:
BIOLOGIA
Année:
2020
Type de document:
Article
Pays d'affiliation:
Portugal