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Electrochemical Tip-Enhanced Raman Spectroscopy: An In Situ Nanospectroscopy for Electrochemistry.
Huang, Sheng-Chao; Bao, Yi-Fan; Wu, Si-Si; Huang, Teng-Xiang; Sartin, Matthew M; Wang, Xiang; Ren, Bin.
Affiliation
  • Huang SC; State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China; email: wangxiang@xmu.edu.cn, bren@xmu.edu.cn.
  • Bao YF; State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China; email: wangxiang@xmu.edu.cn, bren@xmu.edu.cn.
  • Wu SS; State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China; email: wangxiang@xmu.edu.cn, bren@xmu.edu.cn.
  • Huang TX; State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China; email: wangxiang@xmu.edu.cn, bren@xmu.edu.cn.
  • Sartin MM; State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China; email: wangxiang@xmu.edu.cn, bren@xmu.edu.cn.
  • Wang X; State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China; email: wangxiang@xmu.edu.cn, bren@xmu.edu.cn.
  • Ren B; State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China; email: wangxiang@xmu.edu.cn, bren@xmu.edu.cn.
Annu Rev Phys Chem ; 72: 213-234, 2021 Apr 20.
Article de En | MEDLINE | ID: mdl-33400554
ABSTRACT
Revealing the intrinsic relationships between the structure, properties, and performance of the electrochemical interface is a long-term goal in the electrochemistry and surface science communities because it could facilitate the rational design of electrochemical devices. Achieving this goal requires in situ characterization techniques that provide rich chemical information and high spatial resolution. Electrochemical tip-enhanced Raman spectroscopy (EC-TERS), which provides molecular fingerprint information with nanometer-scale spatial resolution, is a promising technique for achieving this goal. Since the first demonstration of this technique in 2015, EC-TERS has been developed for characterizing various electrochemical processes at the nanoscale and molecular level. Here, we review the development of EC-TERS over the past 5 years. We discuss progress in addressing the technical challenges, including optimizing the EC-TERS setup and solving tip-related issues, and provide experimental guidelines. We also survey the important applications of EC-TERS for probing molecular protonation, molecular adsorption, electrochemical reactions, and photoelectrochemical reactions. Finally, we discuss the opportunities and challenges in the future development of this young technique.
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Texte intégral: 1 Collection: 01-internacional Base de données: MEDLINE Type d'étude: Qualitative_research Langue: En Journal: Annu Rev Phys Chem Année: 2021 Type de document: Article
Texte intégral
Ajouter à My VHL
Imprimer
XML
PubMed Links
Recherche sur Google

Texte intégral: 1 Collection: 01-internacional Base de données: MEDLINE Type d'étude: Qualitative_research Langue: En Journal: Annu Rev Phys Chem Année: 2021 Type de document: Article