Understanding electrochemical cation insertion into prussian blue from electrode deformation and mass changes.
Chem Commun (Camb)
; 57(55): 6744-6747, 2021 Jul 14.
Article
de En
| MEDLINE
| ID: mdl-34137403
Alkali ion insertion into Prussian blue from aqueous electrolytes is characterized with operando AFM and EQCM, showing coupling of current with deformation and mass change rates. Stable cycling occurs only with K+, attributed to its lower hydration energy. The (de)insertion of K+ results in reversible deformation even in the open framework structure.
Texte intégral:
1
Collection:
01-internacional
Base de données:
MEDLINE
Langue:
En
Journal:
Chem Commun (Camb)
Sujet du journal:
QUIMICA
Année:
2021
Type de document:
Article
Pays d'affiliation:
États-Unis d'Amérique
Pays de publication:
Royaume-Uni