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Recent Advances in the Synthesis and Transformation of Carbamoyl Fluorides, Fluoroformates, and Their Analogues.
Liu, Lei; Gu, Yu-Cheng; Zhang, Cheng-Pan.
Affiliation
  • Liu L; School of Materials Science and Engineering & School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology, 122 Luoshi Road, Wuhan, 430070, China.
  • Gu YC; Syngenta, Jealott's Hill International Research Centre, Bracknell, Berkshire, RG426EY, UK.
  • Zhang CP; School of Materials Science and Engineering & School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology, 122 Luoshi Road, Wuhan, 430070, China.
Chem Rec ; 23(9): e202300071, 2023 Sep.
Article de En | MEDLINE | ID: mdl-37098875
Carbamoyl fluorides, fluoroformates, and their analogues are a class of important compounds and have been evidenced as versatile building blocks for the preparation of useful molecules in organic chemistry. While major achievements were made in the synthesis of carbamoyl fluorides, fluoroformates, and their analogues in the last half of 20th century, an increasing number of reports have focused on using O/S/Se=CF2 species or their equivalents as the fluorocarbonylation reagents for the direct construction of these compounds from the parent heteroatom-nucleophiles in recent years. This review mainly summarizes the advances in the synthesis and typical application of carbamoyl fluorides, fluoroformates, and their analogues by the halide exchanges and fluorocarbonylation reactions since 1980.
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Texte intégral: 1 Collection: 01-internacional Base de données: MEDLINE Langue: En Journal: Chem Rec Sujet du journal: QUIMICA Année: 2023 Type de document: Article Pays d'affiliation: Chine Pays de publication: États-Unis d'Amérique

Texte intégral: 1 Collection: 01-internacional Base de données: MEDLINE Langue: En Journal: Chem Rec Sujet du journal: QUIMICA Année: 2023 Type de document: Article Pays d'affiliation: Chine Pays de publication: États-Unis d'Amérique