Ring expansion reactions of PîO-containing molecules.
Chem Commun (Camb)
; 59(51): 7927-7930, 2023 Jun 22.
Article
de En
| MEDLINE
| ID: mdl-37278604
ABSTRACT
A series of ring expansion reactions of PîO-containing molecules have been developed for the synthesis of medium-sized ring cyclic phosphonate esters and phosphonamidates. The reactivity trends initially appear to be counter-intuitive, compared with more well established ring expansion reactions of lactam derivatives, but are explained by considering the differences in heteroatom bonding to P and C respectively.
Texte intégral:
1
Collection:
01-internacional
Base de données:
MEDLINE
Sujet principal:
Phosphonates
/
Lactames
Langue:
En
Journal:
Chem Commun (Camb)
Sujet du journal:
QUIMICA
Année:
2023
Type de document:
Article
Pays d'affiliation:
Royaume-Uni