Meso-Formyl, Vinyl, and Ethynyl Porphyrins-Multipotent Synthons for Obtaining a Diverse Array of Functional Derivatives.
Molecules
; 28(15)2023 Jul 31.
Article
de En
| MEDLINE
| ID: mdl-37570752
ABSTRACT
This review presents a strategy for obtaining various functional derivatives of tetrapyrrole compounds based on transformations of unsaturated carbon-oxygen and carbon-carbon bonds of the substituents at the meso position (meso-formyl, vinyl, and ethynyl porphyrins). First, synthetic approaches to the preparation of these precursors are described. Then diverse pathways for the transformations of the multipotent synthons are discussed, revealing a variety of products of such reactions. The structures, electronic, and optical properties of the compounds obtained by the methods under consideration are analyzed. In addition, there is an overview of the applications of the products obtained. Biomedical use of the compounds is among the most important. Finally, the advantages of using the reviewed synthetic strategy to obtain dyes with targeted properties are highlighted.
Texte intégral:
1
Collection:
01-internacional
Base de données:
MEDLINE
Langue:
En
Journal:
Molecules
Sujet du journal:
BIOLOGIA
Année:
2023
Type de document:
Article
Pays d'affiliation:
Russie