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Vanadium-catalysed regioselective hydroboration of epoxides for synthesis of secondary alcohols.
Zhang, Guoqi; Zeng, Haisu; Tang, Quan; Ates, Selin; Zheng, Shengping; Neary, Michelle C.
Affiliation
  • Zhang G; Department of Sciences, John Jay College and PhD Program in Chemistry, The Graduate Center, The City University of New York, New York, NY 10019, USA. guzhang@jjay.cuny.edu.
  • Zeng H; Department of Sciences, John Jay College and PhD Program in Chemistry, The Graduate Center, The City University of New York, New York, NY 10019, USA. guzhang@jjay.cuny.edu.
  • Tang Q; Department of Chemistry, Hunter College, the City University of New York, New York, 10065 NY, USA.
  • Ates S; Department of Sciences, John Jay College and PhD Program in Chemistry, The Graduate Center, The City University of New York, New York, NY 10019, USA. guzhang@jjay.cuny.edu.
  • Zheng S; Department of Sciences, John Jay College and PhD Program in Chemistry, The Graduate Center, The City University of New York, New York, NY 10019, USA. guzhang@jjay.cuny.edu.
  • Neary MC; Department of Chemistry, Hunter College, the City University of New York, New York, 10065 NY, USA.
Dalton Trans ; 52(33): 11395-11400, 2023 Aug 22.
Article de En | MEDLINE | ID: mdl-37577840
ABSTRACT
Regioselective epoxide ring-opening through hydroboration catalysed by a vanadium(III) dialkyl complex supported by a redox-active terpyridine ligand is reported. Secondary alcohols were obtained in high yields via effective Markovnikov hydroboration of terminal epoxides, showcasing a new catalytic application of an earth-abundant vanadium(III) complex.
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Texte intégral: 1 Collection: 01-internacional Base de données: MEDLINE Langue: En Journal: Dalton Trans Sujet du journal: QUIMICA Année: 2023 Type de document: Article Pays d'affiliation: États-Unis d'Amérique
Texte intégral
Ajouter à My VHL
Imprimer
XML
PubMed Links
Recherche sur Google

Texte intégral: 1 Collection: 01-internacional Base de données: MEDLINE Langue: En Journal: Dalton Trans Sujet du journal: QUIMICA Année: 2023 Type de document: Article Pays d'affiliation: États-Unis d'Amérique