Manganese-promoted reductive cross-coupling of disulfides with dialkyl carbonates.
Chem Commun (Camb)
; 59(97): 14439-14442, 2023 Dec 05.
Article
de En
| MEDLINE
| ID: mdl-37982295
ABSTRACT
Manganese is a cheap and environmentally friendly metal on Earth. Herein, we report a manganese-promoted reductive cross-coupling using easily available and odorless disulfides as thiolating agents in an excellent 100% sulfur atom economy. The protocol featured a broad substrate scope, including various alkyl disulfides and excellent functional group compatibility, constructing diverse thioethers under simple conditions. Ultimately, thioethers can be prepared in gram-scale reactions and further transformed into structurally complex molecules.
Texte intégral:
1
Collection:
01-internacional
Base de données:
MEDLINE
Langue:
En
Journal:
Chem Commun (Camb)
Sujet du journal:
QUIMICA
Année:
2023
Type de document:
Article
Pays d'affiliation:
Chine