Formulating of the sustained release of Tebuconazole pesticide using chitosan aerogel reinforced NFC/CaCO3 nanocomposite.

ABSTRACT

Chitosan-based aerogels were fabricated through utilizing of nanofibrillated cellulose (NFC)/CaCO3 composites. Chitosan aerogel and extra three aerogels loaded different concentrations of NFC/CaCO3 were investigated to explore their release efficiency of Tebuconazole pesticides. Results obtained from ATR-FTIR showed a remarkable decline of the characterized chitosan hydroxyl group peak prolonging with appearance of new peaks assigned to the inclusion of inorganic calcium element. Also, SEM images showed chitosan aerogel with regular porous structure increased by incorporation with of NFC/CaCO3 nanocomposite, while EDS affirmed the presence of calcium element rather pristine chitosan aerogel. In addition to this, the physical characterizations showed significant improvement in swelling properties for aerogels incorporated NFC/CaCO3 nanocomposite at low ratios. Chitosan aerogel reinforced NFC/CaCO3 nanocomposite exhibited benefit on loading and release efficiency of Tebuconazole. All samples showed accessibility to column release method with fastest release at low slow rate 2 mL/min as giving chance for diffusion and solubility of ingredient, while release increase as heat increase as result of pore expansion. In conclusion, chitosan aerogels incorporated calcium carbonate showed better-sustained release of Tebuconazole pesticides than pristine chitosan aerogel. The produced aerogels loaded NFC/CaCO3 nanocomposite could be promising for controlled release of pesticides at water-streams in agriculture sector.