Ni-Catalyzed Stereoconvergent Reductive Dimerization of Bromocyclobutenes.
Org Lett
; 26(1): 355-359, 2024 Jan 12.
Article
de En
| MEDLINE
| ID: mdl-38147458
ABSTRACT
A nickel-catalyzed reductive dimerization of bromocyclobutenes to produce unusual and unprecedented cyclobutene dimers was developed. In a stereoconvergent procedure, various bromocyclobutenes were readily dimerized in good yields, with good diastereoselectivities and broad functional group tolerance. Notably, the presence of a carbonyl group in the starting material appears to dictate diastereoselectivity.
Texte intégral:
1
Collection:
01-internacional
Base de données:
MEDLINE
Langue:
En
Journal:
Org Lett
Sujet du journal:
BIOQUIMICA
Année:
2024
Type de document:
Article
Pays d'affiliation:
Autriche