From a mercury(II) bis(yldiide) complex to actinide yldiides.
Chem Commun (Camb)
; 60(23): 3190-3193, 2024 Mar 14.
Article
de En
| MEDLINE
| ID: mdl-38415283
ABSTRACT
The bis(yldiide) mercury complex, (L-Hg-L) [L = C(PPh3)P(S)Ph2], is prepared from the corresponding potassium yldiide and used to access the first substituted yldiide actinide complexes [(C5Me5)2An(L)(Cl)] (An = U, Th) via salt metathesis. Compared to previously reported phosphinocarbene complexes, the complexes exhibit long actinide-carbon distances, which can be explained by the strong polarization of the π-electron density toward carbon.
Texte intégral:
1
Collection:
01-internacional
Base de données:
MEDLINE
Langue:
En
Journal:
Chem Commun (Camb)
Sujet du journal:
QUIMICA
Année:
2024
Type de document:
Article
Pays d'affiliation:
États-Unis d'Amérique
Pays de publication:
Royaume-Uni