The novel up/down-conversion dual-emission carbon dots for dual-channel ratiometric fluorescence detection of pH and Cu2.
Spectrochim Acta A Mol Biomol Spectrosc
; 320: 124648, 2024 Nov 05.
Article
de En
| MEDLINE
| ID: mdl-38885570
ABSTRACT
Up/down-conversion dual-emission carbon dots (U/D-CDs) are rare and have potential in analytical sensing. Herein, a kind of novel U/D-CDs was prepared successfully by a one-step solvothermal method. The prepared U/D-CDs exhibited similar dual-emission behaviors at excitation wavelengths of 300 nm and 680 nm, respectively. In addition, U/D-CDs displayed good photostability and salt-resistance. Due to the protonation-deprotonation, U/D-CDs showed strong pH dependence in the pH range of 2.0-8.0, which developed an up/down-conversion dual-channel ratiometric fluorescence (FL) probe of pH. The FL intensity of U/D-CDs can be effectively quenched by Cu2+ through the static quenching effect. Meanwhile, an obvious color change from yellow-green to blue can be observed under ultraviolet light with the increase of Cu2+ concentration. The up/down-conversion dual-channel ratiometric fluorescence sensor can be used for the visual sensing of pH and Cu2+, which also eliminates background signals and improves its accuracy and selectivity in complex samples.
Texte intégral:
1
Collection:
01-internacional
Base de données:
MEDLINE
Langue:
En
Journal:
Spectrochim Acta A Mol Biomol Spectrosc
Sujet du journal:
BIOLOGIA MOLECULAR
Année:
2024
Type de document:
Article