Crystal structure optimization of copper oxides for the benzyl alcohol oxidation reaction.

Sun, Hainan; Li, Lili; Chen, Yahui; Kim, Yong Beom; Kim, Hyunseung; Fei, Liangshuang; Shao, Zongping; Jung, WooChul

Sun, Hainan; Li, Lili; Chen, Yahui; Kim, Yong Beom; Kim, Hyunseung; Fei, Liangshuang; Shao, Zongping; Jung, WooChul.

Affiliation

Sun H; School of Chemistry and Chemical Engineering, Nantong University, Nantong, 226019, China.
Li L; Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon, 34141, Republic of Korea. wcjung@kaist.ac.kr.
Chen Y; State Key Lab of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan, 250100, China.
Kim YB; State Key Laboratory of Fine Chemicals, College of Materials Science and Engineering, Shenzhen University, Shenzhen, 518071, China.
Kim H; Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon, 34141, Republic of Korea. wcjung@kaist.ac.kr.
Fei L; Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon, 34141, Republic of Korea. wcjung@kaist.ac.kr.
Shao Z; State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing, 211816, China.
Jung W; WA School of Mines: Minerals Energy and Chemical Engineering (WASM-MECE), Curtin University, Perth, Western Australia 6102, Australia. zongping.shao@curtin.edu.au.

Chem Commun (Camb) ; 60(56): 7224-7227, 2024 Jul 09.

Article de En | MEDLINE | ID: mdl-38912646

ABSTRACT

ABSTRACT

In this work, experimental and theoretical analyses reveal that different types of Cu wires significantly change the adsorption properties of reactant molecules and the benzyl alcohol oxidation reaction performance. In particular, CuO nanowires in situ grown on Cu foam exhibit the best performance with a low potential of 1.39 V at a current density of 200 mA cm-2, high selectivity to benzoic acid production, and good operational stability.

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Texte intégral: 1 Collection: 01-internacional Base de données: MEDLINE Langue: En Journal: Chem Commun (Camb) Sujet du journal: QUIMICA Année: 2024 Type de document: Article Pays d'affiliation: Chine Pays de publication: ENGLAND / ESCOCIA / GB / GREAT BRITAIN / INGLATERRA / REINO UNIDO / SCOTLAND / UK / UNITED KINGDOM

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