Synthesis, Crystal Structures and Catalytic Oxidation Property of Two Oxidovanadium(V) Complexes with Schiff bases.
Acta Chim Slov
; 71(2): 288-294, 2024 May 22.
Article
de En
| MEDLINE
| ID: mdl-38919095
ABSTRACT
Two new oxidovanadium(V) complexes, [VO2L1] (1) and [V2O2(µ-O)2L2)] (2), where L1 and L2 are the deprotonated form of 5-bromo-2-(((2-(pyrrolidin-1-yl)ethyl)imino)methyl)phenol (HL1) and 5-bromo-2-(((2-((2-hydroxyethyl)amino)ethyl)imino)methyl)phenol (HL2), respectively, have been synthesized and structurally characterized by physico-chemical methods and single crystal X-ray determination. X-ray analysis indicates that the V atom in complex 1 is in square pyramidal coordination, and those in complex 2 are in octahedral coordination. Crystal structures of the complexes are stabilized by hydrogen bonds. The catalytic property for epoxidation of styrene by the complexes was evaluated.
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1
Collection:
01-internacional
Base de données:
MEDLINE
Langue:
En
Journal:
Acta Chim Slov
Année:
2024
Type de document:
Article