In situ reconstructured alloy nanosheets heterojunction for highly selective electrochemical CO2 reduction to formate.
Chemistry
; : e202402301, 2024 Jul 29.
Article
de En
| MEDLINE
| ID: mdl-39073706
ABSTRACT
Tin (Sn)-based materials are expected to realize efficient CO2 electroreduction into formate. Herein, we constructed a heterojunction by depositing Cu on Cu-doped SnS2 nanosheets. During the electrochemical reaction, this heterojunction evolves to a highly active phase of Cu2O@Cu6Sn5 while maintaining its two-dimensional morphology. Specifically, a partial current density of 35 mA cm-2 with an impressive faradaic efficiency of 93% for formate production was achieved over the evolved heterojunction. In situ and ex situ experiments elucidated the formation mechanism of the Cu2O@Cu6Sn5 heterojunction. Cu6Sn5 nanosheets were formed via a stepwise desulfurization process, while Cu2O was generated through its reaction with hydroxyl radicals. This evolved heterojunction with a high electrochemically active surface area synergistically stabilized the *OCHO intermediate, thereby significantly enhancing the selectivity and activity. Our findings provide insight into the structural evolution process and guide the development of selective electrocatalysts for CO2 reduction.
Texte intégral:
1
Collection:
01-internacional
Base de données:
MEDLINE
Langue:
En
Journal:
Chemistry
Sujet du journal:
QUIMICA
Année:
2024
Type de document:
Article
Pays d'affiliation:
Chine
Pays de publication:
Allemagne