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Copper-catalyzed nucleophilic trifluoromethylation of propargylic halides.
Miyake, Yoshihiro; Ota, Shin-ichi; Shibata, Masashi; Nakajima, Kazunari; Nishibayashi, Yoshiaki.
Affiliation
  • Miyake Y; Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi, Tokyo 113-8656, Japan.
Chem Commun (Camb) ; 49(71): 7809-11, 2013 Sep 14.
Article in En | MEDLINE | ID: mdl-23884450
ABSTRACT
Reactions of propargylic halides with trifluoromethyltrimethylsilane in the presence of a catalytic amount of copper(I) thiophene-2-carboxylate (CuTC) have been found to give the corresponding trifluoromethylated products in good to high yields with a high selectivity.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Copper Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2013 Document type: Article Affiliation country:
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Copper Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2013 Document type: Article Affiliation country: