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Pt nanoparticles entrapped in titanate nanotubes (TNT) for phenol hydrogenation: the confinement effect of TNT.
Yang, Xu; Yu, Xiang; Long, Lizhen; Wang, Tiejun; Ma, Longlong; Wu, Liangpeng; Bai, Yu; Li, Xinjun; Liao, Shijun.
Affiliation
  • Yang X; Key Lab of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Science, Guangzhou, China 510640. lixj@ms.giec.ac.cn.
Chem Commun (Camb) ; 50(21): 2794-6, 2014 Mar 14.
Article in En | MEDLINE | ID: mdl-24487922
ABSTRACT
A Pt@TNT catalyst with Pt nanoparticles entrapped in titanate nanotubes (TNT) was prepared by hydrophobic modification of the exterior surface of the TNT and impregnation with hexachloroplatinic acid (H2PtCl6) aqueous solution. The catalyst's enhanced activity towards the hydrogenation of phenol (as high as ∼3200 gphenol h(-1) gPt(-1) of qTOF) can be ascribed to the confinement effect.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2014 Document type: Article
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2014 Document type: Article