Your browser doesn't support javascript.
loading
Controlled Orthogonal Self-Assembly of Heterometal-Decorated Coordination Cages.
Liu, Guoliang; Zeller, Matthias; Su, Kongzhao; Pang, Jiandong; Ju, Zhanfeng; Yuan, Daqiang; Hong, Maochun.
Affiliation
  • Liu G; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002, P. R. China.
  • Zeller M; Department of Chemistry, Purdue University, West Lafayette, IN, 47907, USA.
  • Su K; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002, P. R. China.
  • Pang J; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002, P. R. China.
  • Ju Z; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002, P. R. China.
  • Yuan D; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002, P. R. China.
  • Hong M; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002, P. R. China.
Chemistry ; 22(48): 17345-17350, 2016 Nov 21.
Article in En | MEDLINE | ID: mdl-27778381
ABSTRACT
Multiple orthogonal coordinative interactions were utilized to construct heterometal-decorated tetrahedral cages from in situ formed trinuclear ZrIV clusters through the combination with other metal ions such as CuII or PdII . Through effective use of the hard/soft acid/base principle, the orthogonal self-assembly process of Zr-bpydc-CuCl2 (H2 bpydc=2,2-bipyridine-5,5-dicarboxylic acid) can be finely controlled using three strategies post-synthetic metallization, a stepwise metalloligand approach, or a one-pot reaction.
Key words
Fulltext
Add to My VHL
Print
XML
PubMed Links
Search on Google

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chemistry Journal subject: QUIMICA Year: 2016 Document type: Article
Fulltext
Add to My VHL
Print
XML
PubMed Links
Search on Google

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chemistry Journal subject: QUIMICA Year: 2016 Document type: Article