Controlled Orthogonal Self-Assembly of Heterometal-Decorated Coordination Cages.
Chemistry
; 22(48): 17345-17350, 2016 Nov 21.
Article
in En
| MEDLINE
| ID: mdl-27778381
ABSTRACT
Multiple orthogonal coordinative interactions were utilized to construct heterometal-decorated tetrahedral cages from in situ formed trinuclear ZrIV clusters through the combination with other metal ions such as CuII or PdII . Through effective use of the hard/soft acid/base principle, the orthogonal self-assembly process of Zr-bpydc-CuCl2 (H2 bpydc=2,2-bipyridine-5,5-dicarboxylic acid) can be finely controlled using three strategies post-synthetic metallization, a stepwise metalloligand approach, or a one-pot reaction.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chemistry
Journal subject:
QUIMICA
Year:
2016
Document type:
Article