Your browser doesn't support javascript.
loading
The largest Se-4f cluster incorporated polyoxometalate with high Lewis acid-base catalytic activity.
Yao, Meng-Ying; Liu, Yu-Feng; Li, Xin-Xiong; Yang, Guo-Ping; Zheng, Shou-Tian.
Affiliation
  • Yao MY; State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China. lxx@fzu.edu.cn.
  • Liu YF; Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, Jiangxi Province Key Laboratory of Synthetic Chemistry, East China University of Technology, Nanchang 330013, China. erick@ecut.edu.cn.
  • Li XX; State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China. lxx@fzu.edu.cn.
  • Yang GP; Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, Jiangxi Province Key Laboratory of Synthetic Chemistry, East China University of Technology, Nanchang 330013, China. erick@ecut.edu.cn.
  • Zheng ST; State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China. lxx@fzu.edu.cn.
Chem Commun (Camb) ; 58(38): 5737-5740, 2022 May 10.
Article in En | MEDLINE | ID: mdl-35445228
A 4p-4f cluster incorporated polyoxometalate (POM), namely, H18{[(H4pic)4Eu10Se13O28(H2O)12](α-GeW9O34)4·40H2O (1-Eu, H4pic = isonicotinic acid), has been first synthesized and characterized. 1-Eu features an interesting four-shell structure, representing the largest Se-4f cluster incorporated POM known to date. Besides, 1-Eu exhibits excellent Lewis acid-base catalytic activity and reusablity in catalyzing the gram-scale dehydration condensation reaction of hydrazines and 1,3-diketones to synthesize polysubstituted pyrazoles.
Fulltext
Add to My VHL
Print
XML
PubMed Links
Search on Google

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2022 Document type: Article Affiliation country: Country of publication:
Fulltext
Add to My VHL
Print
XML
PubMed Links
Search on Google

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2022 Document type: Article Affiliation country: Country of publication: