Binary organic-inorganic nanocomposite of polyaniline-MnO2 for non-enzymatic electrochemical detection of environmental pollutant nitrite.

Due to wide usage as nitrogen fertilizer in agriculture and food additive in industry, nitrite, as one of inorganic environmental pollutants, could cause detrimental effects to the ecological environment. Therefore, accurate, sensitive and rapid detection of nitrite is necessary. In this work, binary hybrid polyaniline-MnO2 organic-inorganic nanocomposite is prepared chemically and characterized via X-ray diffraction spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy and energy-dispersive X-ray spectroscopy. Polyaniline-MnO2 organic-inorganic nanocomposite serves as excellent electrode modifier for electrochemical sensing of nitrite by two modes of cyclic voltammetry and chronoamperometry, achieving broad linear ranges and low limits of detection for both methods. Moreover, the organic-inorganic nanocomposite displays satisfactory sensing performance in real water sample analysis. Amine and imino groups of polyaniline contribute to the better adsorption behavior of nitrite onto the nanocomposite, which improves the nanocomposite's sensing performance. In summary, the synergistic effects between polyaniline and MnO2 is taken advantaged in the nanocomposite for effective electrochemical sensor development.