Your browser doesn't support javascript.
loading
TBPEH-TBPB Initiate the Radical Addition of Benzaldehyde and Allyl Esters.
Sun, Binlong; Tian, Xiaoyu; Yang, Sen; Wang, Yingying; Shao, Yingying; Fu, Xinhao; Wang, Wenyuan; Tu, Minting; Chen, Yang; Wu, Junhui; Wu, Changyuan; Tan, Chengxia.
Affiliation
  • Sun B; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Tian X; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Yang S; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Wang Y; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Shao Y; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Fu X; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Wang W; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Tu M; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Chen Y; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Wu J; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Wu C; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Tan C; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
Int J Mol Sci ; 23(22)2022 Nov 08.
Article in En | MEDLINE | ID: mdl-36430186
ABSTRACT
Tert-butylperoxy-2-ethylhexanoate (TBPEH) and tert-butyl peroxybenzoate (TBPB) promote the radical acylation of allyl ester with benzaldehyde to synthesize new carbonyl-containing compounds under solvent-free and metal-free conditions. This reaction is compatible with electron-donating and halogen groups and has excellent atom utilization and chemical selectivity. Furthermore, the synthetic compounds can further apply to the preparation of lactone, piperidine, tetrazole and oxazole.
Subject(s)
Key words
Fulltext
Add to My VHL
Print
XML
PubMed Links
Search on Google

Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Benzaldehydes / Esters Language: En Journal: Int J Mol Sci Year: 2022 Document type: Article Affiliation country:
Fulltext
Add to My VHL
Print
XML
PubMed Links
Search on Google

Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Benzaldehydes / Esters Language: En Journal: Int J Mol Sci Year: 2022 Document type: Article Affiliation country: