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Quinoid-Thiophene-Based Covalent Organic Polymers for High Iodine Uptake: When Rational Chemical Design Counterbalances the Low Surface Area and Pore Volume.
Yildirim, Onur; Tsaturyan, Arshak; Damin, Alessandro; Nejrotti, Stefano; Crocellà, Valentina; Gallo, Angelo; Chierotti, Michele Remo; Bonomo, Matteo; Barolo, Claudia.
Affiliation
  • Yildirim O; Department of Chemistry and NIS Interdepartmental Centre, University of Turin, Via Pietro Giuria 7, 10125 Torino, Italy.
  • Tsaturyan A; Department of Chemistry and NIS Interdepartmental Centre, University of Turin, Via Pietro Giuria 7, 10125 Torino, Italy.
  • Damin A; Institute of Physical and Organic Chemistry, Southern Federal University, 344006 Rostov-on-Don, Russia.
  • Nejrotti S; Université Jean Monnet Saint-Etienne, CNRS, Institut d'Optique Graduate School, Laboratoire Hubert Curien UMR 5516, F-42023 Saintt-Etienne, France.
  • Crocellà V; Department of Chemistry and NIS Interdepartmental Centre, University of Turin, Via Pietro Giuria 7, 10125 Torino, Italy.
  • Gallo A; INSTM Reference Centre, Università degli Studi di Torino, Via Gioacchino Quarello 15/a, 10125 Torino, Italy.
  • Chierotti MR; Department of Chemistry and NIS Interdepartmental Centre, University of Turin, Via Pietro Giuria 7, 10125 Torino, Italy.
  • Bonomo M; INSTM Reference Centre, Università degli Studi di Torino, Via Gioacchino Quarello 15/a, 10125 Torino, Italy.
  • Barolo C; Department of Chemistry and NIS Interdepartmental Centre, University of Turin, Via Pietro Giuria 7, 10125 Torino, Italy.
ACS Appl Mater Interfaces ; 15(12): 15819-15831, 2023 Mar 29.
Article in En | MEDLINE | ID: mdl-36926827
A novel 2D covalent organic polymer (COP), based on conjugated quinoid-oligothiophene (QOT) and tris(aminophenyl) benzene (TAPB) moieties, is designed and synthesized (TAPB-QOT COP). Some DFT calculations are made to clarify the equilibrium between different QOT isomers and how they could affect the COP formation. Once synthetized, the polymer has been thoroughly characterized by spectroscopic (i.e., Raman, UV-vis), SSNMR and surface (e.g., SEM, BET) techniques, showing a modest surface area (113 m2 g-1) and micropore volume (0.014 cm3 g-1 with an averaged pore size of 5.6-8 Å). Notwithstanding this, TAPB-QOT COP shows a remarkably high iodine (I2) uptake capacity (464 %wt) comparable to or even higher than state-of-the-art porous organic polymers (POPs). These auspicious values are due to the thoughtful design of the polymer with embedded sulfur sites and a conjugated scaffold with the ability to counterbalance the relatively low pore volumes. Indeed, both morphological and Raman data, supported by computational analyses, prove the very high affinity between the S atom in our COP and the I2. As a result, TAPB-QOT COP shows the highest volumetric I2 uptake (i.e., the amount of I2 uptaken per volume unit) up to 331 g cm-3 coupled with a remarkably high reversibility (>80% after five cycles).
Key words

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: ACS Appl Mater Interfaces Journal subject: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Year: 2023 Document type: Article Affiliation country: Country of publication:

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: ACS Appl Mater Interfaces Journal subject: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Year: 2023 Document type: Article Affiliation country: Country of publication: