Comments on "Facilely synthesized cobalt doped hydroxyapatite as hydroxyl promoted peroxymonosulfate activator for degradation of Rhodamine B".

ABSTRACT

In recent years, researchers have devoted themselves to developing composites containing cobalt as highly active heterogeneous catalysts of persulfate. Most of them reported that the catalytic degradation processes of organic pollutants were accompanied by the leaching of cobalt ions, but only a few studies considered the contribution of the dissolved cobalt ion to the degradation of organic compounds. A research paper in Journal of Hazardous Materials reported a study on synthesis, application and catalytic mechanisms of cobalt doped hydroxyapatite (Co-HAP) for Rhodamine B (RhB) degradation. We find that non-main catalytic mechanisms were listed and that the effect of Co-HAP was overestimated.