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B(3,4,5-F3H2C6)3 Lewis acid-catalysed C3-allylation of indoles.
Alotaibi, Nusaybah; Babaahmadi, Rasool; Pramanik, Milan; Kaehler, Tanja; Dasgupta, Ayan; Richards, Emma; Ariafard, Alireza; Wirth, Thomas; Melen, Rebecca L.
Affiliation
  • Alotaibi N; Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Translational Research Hub, Maindy Road, Cathays, Cardiff, CF24 4HQ, Cymru/Wales, UK. MelenR@cardiff.ac.uk.
  • Babaahmadi R; Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Translational Research Hub, Maindy Road, Cathays, Cardiff, CF24 4HQ, Cymru/Wales, UK. MelenR@cardiff.ac.uk.
  • Pramanik M; Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Translational Research Hub, Maindy Road, Cathays, Cardiff, CF24 4HQ, Cymru/Wales, UK. MelenR@cardiff.ac.uk.
  • Kaehler T; Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Translational Research Hub, Maindy Road, Cathays, Cardiff, CF24 4HQ, Cymru/Wales, UK. MelenR@cardiff.ac.uk.
  • Dasgupta A; Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Translational Research Hub, Maindy Road, Cathays, Cardiff, CF24 4HQ, Cymru/Wales, UK. MelenR@cardiff.ac.uk.
  • Richards E; Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford, OX1 3TA, UK.
  • Ariafard A; Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Translational Research Hub, Maindy Road, Cathays, Cardiff, CF24 4HQ, Cymru/Wales, UK. MelenR@cardiff.ac.uk.
  • Wirth T; School of Natural Sciences (Chemistry), University of Tasmania, Private Bag 75, Hobart, Tasmania, 7001 Australia.
  • Melen RL; School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, Cymru/Wales, UK.
Dalton Trans ; 52(16): 5039-5043, 2023 Apr 25.
Article in En | MEDLINE | ID: mdl-37063050
ABSTRACT
Herein we report the B(3,4,5-F3H2C6)3-catalysed C3-allylation of indoles using allylic esters. 25 examples of C3-allylated products are presented in up to 97% yield. The mechanism for the reaction was explored using detailed Density Functional Theory (DFT) studies.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2023 Document type: Article Affiliation country: Publication country: ENGLAND / ESCOCIA / GB / GREAT BRITAIN / INGLATERRA / REINO UNIDO / SCOTLAND / UK / UNITED KINGDOM
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2023 Document type: Article Affiliation country: Publication country: ENGLAND / ESCOCIA / GB / GREAT BRITAIN / INGLATERRA / REINO UNIDO / SCOTLAND / UK / UNITED KINGDOM