Non-Fermi-Liquid Behavior of Superconducting SnH4.

ABSTRACT

The chemical interaction of Sn with H2 by X-ray diffraction methods at pressures of 180-210 GPa is studied. A previously unknown tetrahydride SnH4 with a cubic structure (fcc) exhibiting superconducting properties below TC  = 72 K is obtained; the formation of a high molecular C2/m-SnH14 superhydride and several lower hydrides, fcc SnH2 , and C2-Sn12 H18 , is also detected. The temperature dependence of critical current density JC (T) in SnH4 yields the superconducting gap 2Δ(0) = 21.6 meV at 180 GPa. SnH4 has unusual behavior in strong magnetic fields B,T-linear dependences of magnetoresistance and the upper critical magnetic field BC2 (T) ∝ (TC - T). The latter contradicts the Wertheimer-Helfand-Hohenberg model developed for conventional superconductors. Along with this, the temperature dependence of electrical resistance of fcc SnH4 in non-superconducting state exhibits a deviation from what is expected for phonon-mediated scattering described by the Bloch-Grüneisen model and is beyond the framework of the Fermi liquid theory. Such anomalies occur for many superhydrides, making them much closer to cuprates than previously believed.