Control of functionalized single-walled carbon nanotube photoluminescence <i>via</i> competition between thermal rearrangement and elimination.

Maeda, Yutaka; Morooka, Rina; Zhao, Pei; Yamada, Michio; Ehara, Masahiro

Control of functionalized single-walled carbon nanotube photoluminescence via competition between thermal rearrangement and elimination.

Maeda, Yutaka; Morooka, Rina; Zhao, Pei; Yamada, Michio; Ehara, Masahiro.

Affiliation

Maeda Y; Department of Chemistry, Tokyo Gakugei University, Tokyo 184-8501, Japan. ymaeda@u-gakugei.ac.jp.
Morooka R; Department of Chemistry, Tokyo Gakugei University, Tokyo 184-8501, Japan. ymaeda@u-gakugei.ac.jp.
Zhao P; Research Center for Computational Science, Institute for Molecular Science, Okazaki 444-8585, Japan. pei@ims.ac.jp.
Yamada M; Department of Chemistry, Tokyo Gakugei University, Tokyo 184-8501, Japan. ymaeda@u-gakugei.ac.jp.
Ehara M; Research Center for Computational Science, Institute for Molecular Science, Okazaki 444-8585, Japan. pei@ims.ac.jp.

Chem Commun (Camb) ; 59(78): 11648-11651, 2023 Sep 28.

Article in En | MEDLINE | ID: mdl-37655792

ABSTRACT

ABSTRACT

We conducted the chiral separation of functionalized single-walled carbon nanotubes (SWNTs) with dibromopropane derivatives. Depending on their chirality and diameter, the thermal treatment of functionalized SWNTs leads to a shift in the emission radiation to longer wavelengths owing to rearrangement reaction in competition with elimination reaction.

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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2023 Document type: Article Affiliation country: Country of publication: ENGLAND / ESCOCIA / GB / GREAT BRITAIN / INGLATERRA / REINO UNIDO / SCOTLAND / UK / UNITED KINGDOM

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