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Influence of solvent on cyclic polynorbornene tacticity.
Hyun, Sung-Min; Marathianos, Arkadios; Boeck, Parker T; Ghiviriga, Ion; Lester, Daniel W; Sumerlin, Brent S; Veige, Adam S.
Affiliation
  • Hyun SM; University of Florida, Department of Chemistry, Center for Catalysis, P.O. Box 117200, Gainesville, FL, 32611, USA. veige@chem.ufl.edu.
  • Marathianos A; Polymer Characterization Research Technology Platform, University of Warwick, Coventry CV4 7AL, UK.
  • Boeck PT; University of Florida, Department of Chemistry, Center for Catalysis, P.O. Box 117200, Gainesville, FL, 32611, USA. veige@chem.ufl.edu.
  • Ghiviriga I; University of Florida, Department of Chemistry, George and Josephine Butler Polymer Research Laboratory, Center for Macromolecular Science and Engineering, Gainesville, FL 32611, USA.
  • Lester DW; University of Florida, Department of Chemistry, Center for Catalysis, P.O. Box 117200, Gainesville, FL, 32611, USA. veige@chem.ufl.edu.
  • Sumerlin BS; Polymer Characterization Research Technology Platform, University of Warwick, Coventry CV4 7AL, UK.
  • Veige AS; University of Florida, Department of Chemistry, George and Josephine Butler Polymer Research Laboratory, Center for Macromolecular Science and Engineering, Gainesville, FL 32611, USA.
Chem Commun (Camb) ; 59(94): 13993-13996, 2023 Nov 23.
Article in En | MEDLINE | ID: mdl-37938062
Tacticity is critical to polymer properties. The influence of solvent on tacticity in the catalytic synthesis of cyclic polynorbornene (c-PNB) is reported. In toluene cis,syndiotactic c-PNB forms; in THF, cis,syn/iso c-PNB forms.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2023 Document type: Article Affiliation country: Country of publication:
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2023 Document type: Article Affiliation country: Country of publication: