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Photo-induced valence tautomerism and polarization switching in mononuclear cobalt complexes with an enantiopure chiral ligand.
Xu, Wen-Huang; Huang, Yu-Bo; Zheng, Wen-Wei; Su, Sheng-Qun; Kanegawa, Shinji; Wu, Shu-Qi; Sato, Osamu.
Affiliation
  • Xu WH; Institute for Materials Chemistry and Engineering & IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan. sato@cm.kyushu-u.ac.
  • Huang YB; Institute for Materials Chemistry and Engineering & IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan. sato@cm.kyushu-u.ac.
  • Zheng WW; Institute for Materials Chemistry and Engineering & IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan. sato@cm.kyushu-u.ac.
  • Su SQ; Institute for Materials Chemistry and Engineering & IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan. sato@cm.kyushu-u.ac.
  • Kanegawa S; Institute for Materials Chemistry and Engineering & IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan. sato@cm.kyushu-u.ac.
  • Wu SQ; Institute for Materials Chemistry and Engineering & IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan. sato@cm.kyushu-u.ac.
  • Sato O; Institute for Materials Chemistry and Engineering & IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan. sato@cm.kyushu-u.ac.
Dalton Trans ; 53(6): 2512-2516, 2024 Feb 06.
Article in En | MEDLINE | ID: mdl-38224229
ABSTRACT
Light-induced polarization switchable molecular materials have attracted attention for decades owing to their potential remote manipulation and ultrafast responsiveness. Here we report a valence tautomeric (VT) complex with an enantiopure chiral ligand. By a suitable choice of counter anions, a significant improvement in photoconversion has been demonstrated, leading to novel photo-responsive polarization switching materials.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans / Dalton trans (2003. Online) / Dalton transactions (2003. Online) Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: Country of publication:
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans / Dalton trans (2003. Online) / Dalton transactions (2003. Online) Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: Country of publication: