Photophysical Study on the Effect of the External Potential on NiO-Based Photocathodes.
ACS Appl Mater Interfaces
; 16(4): 5217-5224, 2024 Jan 31.
Article
in En
| MEDLINE
| ID: mdl-38235571
ABSTRACT
In the present study, we investigate the effects of the applied external potential on a dye-sensitized NiO photocathode by time-resolved photoluminescence and femtosecond transient absorption spectroscopy under operating conditions. Instead of the anticipated acceleration of photoinduced hole injection from dye into NiO at a more negative applied potential, we observe that both hole injection and charge recombination are slowed down. We cautiously assign this effect to a variation in OH- ion concentration in the inner Helmholtz plane of the electrochemical double layer with applied potential, warranting further investigation for the realization of efficient solar fuel devices.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
ACS Appl Mater Interfaces
Journal subject:
BIOTECNOLOGIA
/
ENGENHARIA BIOMEDICA
Year:
2024
Document type:
Article
Affiliation country: