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{Mo4}-directed structural evolution of highly reduced molybdenum red clusters for efficient proton conduction.
Li, Bingbing; Lan, Yuxin; Su, Heyang; Xu, Jiaxin; Zhao, Qixin; Ma, Yubin; Zheng, Qi; Xuan, Weimin.
Affiliation
  • Li B; State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, P R China. weiminxuan@dhu.edu.cn.
  • Lan Y; State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, P R China. weiminxuan@dhu.edu.cn.
  • Su H; State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, P R China. weiminxuan@dhu.edu.cn.
  • Xu J; State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, P R China. weiminxuan@dhu.edu.cn.
  • Zhao Q; State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, P R China. weiminxuan@dhu.edu.cn.
  • Ma Y; State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, P R China. weiminxuan@dhu.edu.cn.
  • Zheng Q; State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Materials Science and Engineering, Donghua University, Shanghai 201620, P R China. qi.zheng@dhu.edu.cn.
  • Xuan W; State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, P R China. weiminxuan@dhu.edu.cn.
Dalton Trans ; 53(14): 6184-6189, 2024 Apr 02.
Article in En | MEDLINE | ID: mdl-38511430
ABSTRACT
A series of highly reduced Mo red clusters {Mo28} (1), {Mo30} (2), and {Mo40} (3) are synthesized from the rational assembly of planar {MoV4} building blocks and employed for proton conduction. 3 exhibits the best conductivity of 7.56 × 10-3 S cm-1 under optimal conditions due to the most efficient hydrogen-bonding network.

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2024 Document type: Article Country of publication:

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2024 Document type: Article Country of publication: