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Cyanide-bridged one-dimensional ferromagnetic Ru(III)Mn(III) coordination polymer exhibiting a field-induced magnetic phase transition.
Inorg Chem ; 48(3): 816-8, 2009 Feb 02.
Artigo em Inglês | MEDLINE | ID: mdl-19102632
ABSTRACT
A cyanide-linked Ru(III)(4d)-Mn(III)(3d) bimetallic chain complex (1) was prepared by the self-assembly of a ruthenium(III) bicyanide and a Mn(III) Schiff base. Ferromagnetic couplings between the magnetic centers are present within a chain, while antiferromagnetic interactions between chains (T(N) = 2.5 K) transmit. Complex 1 also shows a field-induced magnetic phase transition.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Inorg Chem Ano de publicação: 2009 Tipo de documento: Artigo