Dipolar compounds containing fluorene and a heteroaromatic ring as the conjugating bridge for high-performance dye-sensitized solar cells.
Chemistry
; 16(10): 3184-93, 2010 Mar 08.
Article
em En
| MEDLINE
| ID: mdl-20119994
ABSTRACT
A novel series of dipolar organic dyes containing diarylamine as the electron donor, 2-cyanoacrylic acid as the electron acceptor, and fluorene and a heteroaromatic ring as the conjugating bridge have been developed and characterized. These metal-free dyes exhibited very high molar extinction coefficients in the electronic absorption spectra and have been successfully fabricated as efficient nanocrystalline TiO(2) dye-sensitized solar cells (DSSCs). The solar-energy-to-electricity conversion efficiencies of DSSCs ranged from 4.92 to 6.88%, which reached 68-96% of a standard device of N719 fabricated and measured under the same conditions. With a TiO(2) film thickness of 6 microm, DSSCs based on these dyes had photocurrents surpassing that of the N719-based device. DFT computation results on these dyes also provide detailed structural information in connection with their high cell performance.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chemistry
Assunto da revista:
QUIMICA
Ano de publicação:
2010
Tipo de documento:
Article
País de afiliação:
Taiwan
País de publicação:
ALEMANHA
/
ALEMANIA
/
DE
/
DEUSTCHLAND
/
GERMANY