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Stepwise deposition of metal organic frameworks on flexible synthetic polymer surfaces.
Meilikhov, Mikhail; Yusenko, Kirill; Schollmeyer, Eckhardt; Mayer, Christian; Buschmann, Hans-Jürgen; Fischer, Roland A.
Afiliação
  • Meilikhov M; Department of Inorganic Chemistry II, Ruhr University Bochum, Universitätsstrasse 150, 44780, Bochum, Germany.
Dalton Trans ; 40(18): 4838-41, 2011 May 14.
Artigo em Inglês | MEDLINE | ID: mdl-21465034
ABSTRACT
Thin films of [Cu(3)(btc)(2)](n) (btc = 1,3,5-benzenetricarboxylate) metal organic framework were deposited in a stepwise manner on surfaces of flexible organic polymers. The thickness of films can be precisely controlled. The deposition of the first cycles was monitored by UV-vis spectroscopy. The porosity was proven by the adsorption of pyrazine, which was monitored by FT-IR and thermogravimetric analysis. The deposition of MOF thin films on flexible polymer surfaces might be a new path for the fabrication of functional materials for different applications, such as protection layers for working clothes and gas separation materials in the textile industry.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Dalton Trans Assunto da revista: Química Ano de publicação: 2011 Tipo de documento: Artigo País de afiliação: Alemanha