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Cyanide-bridged W(V)Mn(III) single-chain magnet with isolated Mn(III) moieties exhibiting two types of relaxation dynamics.
Inorg Chem ; 50(22): 11306-8, 2011 Nov 21.
Artigo em Inglês | MEDLINE | ID: mdl-22013958
ABSTRACT
A 5d-3d bimetallic compound was prepared by self-assembling [W(CN)(8)](3-) and the Mn(III) Schiff bases. This neutral complex consists of cyanide-linked W(V)Mn(III) anionic chains and isolated Mn(III) Schiff base cations. We demonstrate that two types of relaxation processes are involved in the system; the low-T dynamics may come from magnetic domain dynamics and the high-T relaxation stems from the anionic chain, revealing single-chain magnet character.
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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Assunto principal: Tungstênio / Cianetos / Imãs / Manganês Idioma: Inglês Revista: Inorg Chem Ano de publicação: 2011 Tipo de documento: Artigo