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Tripodal europium complex with triangulenium dye: a model bifunctional metallo-organic system.
Hamacek, Josef; Besnard, Céline; Mehanna, Nathalie; Lacour, Jérôme.
Afiliação
  • Hamacek J; Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, 30 quai E. Ansermet, 1211 Geneva, Switzerland. Josef.Hamacek@unige.ch
Dalton Trans ; 41(22): 6777-82, 2012 Jun 14.
Artigo em Inglês | MEDLINE | ID: mdl-22523756
ABSTRACT
A new tripodal ligand has been designed by coupling pyridyldicarbonyl binding strands with a triazatriangulenium platform (TATA). The complexation reaction with europium provides a C(3)-symmetrical mononuclear compound that is characterized with NMR, ESMS and qualitatively with single-crystal X-ray crystallography. In addition, photophysical studies of this dual emissive system have been performed, since the combination of the TATA fluorophore with trivalent lanthanides is of potential interest for the further development of imaging applications.
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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Assunto principal: Compostos Organometálicos / Acridinas / Corantes / Európio / Compostos Heterocíclicos de 4 ou mais Anéis Idioma: Inglês Revista: Dalton Trans Assunto da revista: Química Ano de publicação: 2012 Tipo de documento: Artigo País de afiliação: Suíça