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Sm@C2v(3)-C80: site-hopping motion of endohedral Sm atom and metal-induced effect on redox profile.
Nanoscale ; 4(21): 6876-9, 2012 Nov 07.
Artigo em Inglês | MEDLINE | ID: mdl-23023345
ABSTRACT
A new metallofullerene Sm@C(2v)(3)-C(80) was synthesized and characterized. X-Ray analysis showed that the endohedral Sm atom undergoes a hopping motion between several off-center sites, even at low temperature. In addition, a comparative electrochemical study between Sm@C(2v)(3)-C(80) and Yb@C(2v)(3)-C(80) revealed their different redox potentials, suggesting a metal-induced effect on their redox profiles.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Nanoscale Ano de publicação: 2012 Tipo de documento: Artigo