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Access to an unexplored chiral C82  cage by encaging a divalent metal: structural elucidation and electrochemical studies of Sm@C2(5)-C82.
Chemistry ; 18(45): 14246-9, 2012 Nov 05.
Artigo em Inglês | MEDLINE | ID: mdl-23033122
ABSTRACT
Access to a chiral C(82)  cage: Encaging a divalent samarium atom has provided access to an unexplored chiral cage of C(2)(5)-C(82) that has never been reported for trivalent M@C(82) or empty fullerenes. Inside this cage, a wandering Sm atom has been identified using crystallographic methods. In addition, electrochemical studies of Sm@C(2)(5)-C(82) have been performed to explore its oxidation properties (see figure).
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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Assunto principal: Samário / Fulerenos Idioma: Inglês Revista: Chemistry Assunto da revista: Química Ano de publicação: 2012 Tipo de documento: Artigo