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Cooperative spin transition in a mononuclear manganese(III) complex.
Angew Chem Int Ed Engl ; 51(50): 12597-601, 2012 Dec 07.
Artigo em Inglês | MEDLINE | ID: mdl-23129209
ABSTRACT
Mind the gap A complete, cooperative spin transition for a mononuclear Mn(III) complex is reported with an 8 K hysteresis window. Raman spectra collected at a single temperature in warming and cooling modes confirm the electronic bistability within the hysteresis loop. The source of the cooperativity is a disconnection in the hydrogen-bonded 1D chains that connect adjacent cations owing to an order-disorder transition in the PF(6)(-) counterion.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Angew Chem Int Ed Engl Ano de publicação: 2012 Tipo de documento: Artigo País de afiliação: Irlanda