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A clothes-peg-shaped binuclear trans-bis(2-aminotroponato)palladium(II) complex bearing pentamethylene spacers.
Acta Crystallogr C ; 69(Pt 5): 503-5, 2013 May.
Artigo em Inglês | MEDLINE | ID: mdl-23629901
ABSTRACT
rac-Bis{µ-trans-2,2'-[pentane-1,5-diylbis(azanediyl)]ditroponato}dipalladium(II), [Pd2(C19H20N2O2)2], has been synthesized and fully characterized using single-crystal X-ray diffraction, (1)H NMR, FT-IR and mass spectroscopy. The trans coordination, vaulted structure and anti conformation have been unequivocally established from the X-ray diffraction studies. This is the first example of a bis(aminotroponato)palladium complex. In the crystalline state, the molecule has twofold symmetry and each molecular unit undergoes intermolecular offset π-stacking of the tropone rings to afford heterochiral interpenetrating dimers that are aligned in a lamellar manner with a herringbone packing motif.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Acta Crystallogr C Ano de publicação: 2013 Tipo de documento: Artigo País de afiliação: Japão