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Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis-(pyridin-4-yl)pentane linkers.
Acta Crystallogr Sect E Struct Rep Online ; 70(Pt 8): 80-3, 2014 Aug 01.
Artigo em Inglês | MEDLINE | ID: mdl-25249860
ABSTRACT
The title compound, poly[[di-aqua-bis-[1,5-bis-(pyridin-4-yl)pentane-κ(2) NN']cadmium] bis-(perchlorate) 1,5-bis-(pyridin-4-yl)pentane ethanol mono-solvate], [Cd(C15H18N2)2(H2O)2](ClO4)2·C15H18N2·C2H6O, is a layered coordination polymer built up from highly squashed 4(4) nets in which the octa-hedral trans-CdO2N4 nodes (Cd site symmetry -1) are linked by the bifunctional ligands, forming infinite (110) sheets. The cationic sheets are charge-balanced by inter-layer perchlorate ions. A free 1,5-bis-(pyridin-4-yl)pentane mol-ecule and an ethanol mol-ecule of crystallization are also found in the inter-sheet region. A number of O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds help to consolidate the layered structure.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Acta Crystallogr Sect E Struct Rep Online Ano de publicação: 2014 Tipo de documento: Artigo País de afiliação: Reino Unido