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Designing artificial 3D helicates: unprecedented self-assembly of homo-octanuclear tetrapods with europium.
Zebret, Soumaila; Vögele, Eliane; Klumpler, Tomas; Hamacek, Josef.
Afiliação
  • Zebret S; Department of Inorganic and Analytical Chemistry, University of Geneva, 30 quai Ernest-Ansermet, 1211 Geneva 4 (Switzerland).
Chemistry ; 21(18): 6695-9, 2015 Apr 27.
Artigo em Inglês | MEDLINE | ID: mdl-25765709
ABSTRACT
Herein, we report on the rational design, preparation and characterization of a novel homo-octanuclear helicate, which results from a spatial extension of the central tetranuclear platform. The 3D supramolecular assembly is obtained by complexing europium(III) with a new hexatopic tripodal ligand. The isolated octanuclear helicate is fully characterized by different methods clearly evidencing the structure predicted with molecular modelling. The ligand preorganization plays a crucial role in a successful self-assembly process and induces the formation of a well-defined triple-stranded helical structure. This prototypal octanuclear edifice accommodating functional lanthanides within a 3D scaffold offers attractive perspectives for further applications.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Chemistry Assunto da revista: Química Ano de publicação: 2015 Tipo de documento: Artigo