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Single-molecule junctions with epitaxial graphene nanoelectrodes.
Nano Lett ; 15(5): 3512-8, 2015 May 13.
Artigo em Inglês | MEDLINE | ID: mdl-25923590
On the way to ultraflat single-molecule junctions with transparent electrodes, we present a fabrication scheme based on epitaxial graphene nanoelectrodes. As a suitable molecule, we identified a molecular wire with fullerene anchor groups. With these two components, stable electrical characteristics could be recorded. Electrical measurements show that single-molecule junctions with graphene and with gold electrodes display a striking agreement. This motivated a hypothesis that the differential conductance spectra are rather insensitive to the electrode material. It is further corroborated by the assignment of asymmetries and spectral features to internal molecular degrees of freedom. The demonstrated open-access graphene electrodes and the electrode-insensitive molecules provide a model system that will allow for a thorough investigation of an individual single-molecule contact with additional probes.





Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Nano Lett Ano de publicação: 2015 Tipo de documento: Artigo País de afiliação: Alemanha