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Nanoscale Kirkendall growth of silicalite-1 zeolite mesocrystals with controlled mesoporosity and size.
Chem Commun (Camb) ; 51(63): 12563-6, 2015 Aug 14.
Artigo em Inglês | MEDLINE | ID: mdl-26152881
ABSTRACT
The Kirkendall effect was utilized to synthesize mesoporous silicalite-1 zeolite nanocrystals without the involvement of additional templates. The mesopore size as well as the particle size can be easily controlled by nanoscale Kirkendall growth via significantly reducing the amount of water or tetrapropylammonium hydroxide, which were used in large quantities in conventional methods. The Kirkendall growth method is thus suitable for large-scale synthesis of mesoporous MFI zeolites with very high yields but low cost for practical applications.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Chem Commun (Camb) Assunto da revista: Química Ano de publicação: 2015 Tipo de documento: Artigo